[1,2-Bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)copper(II)
نویسندگان
چکیده
In the title compound, [Cu(NO(3))(2)(C(18)H(16)N(2)O(2))], the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions.
منابع مشابه
Bis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]copper(II) tetrahydrate
In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·4H(2)O, the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral geometry environment defined by four O atoms and two N atoms. A chain structure along [100] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules.
متن کامل[1,2-Bis(pyridin-2-ylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)cobalt(II)
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))], the Co(II) ion is six-coordinated in a distorted octa-hedral environment defined by two O and two N atoms from the ligand and by two O atoms from two nitrate anions. A two-dimensional network parallel to the ab plane is built up by C-H⋯O hydrogen bonds, which link adjacent mol-ecules in the crystal structure.
متن کاملBis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]copper(II) monohydrate
In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules.
متن کاملThe cocrystal μ-oxalato-κ4 O 1,O 2:O 1′,O 2′-bis(aqua(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) μ-oxalato-κ4 O 1,O 2:O 1′,O 2′-bis((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II)) (1/1)
The title cocrystal, [Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(H(2)O)(2)][Cu(2)(C(2)O(4))(NO(3))(2)(C(7)H(9)N(3))(2)(CH(4)O)(2)], is a 1:1 cocrystal of two centrosymmetric Cu(II) complexes with oxalate dianions and Schiff base ligands. In each mol-ecule, the Cu(II) centre is in a distorted octa-hedral cis-CuN(2)O(4) environment, the donor atoms of the N,N'-bidentate Schiff base ligand and the...
متن کاملcatena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]
In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010